Properties and Phases:
– Hydrogen is the lightest element, constituting approximately 75% of all normal matter.
– It is colorless, odorless, tasteless, non-toxic, and highly combustible.
– Hydrogen exists in various phases: gaseous, liquid, slush, solid, and metallic hydrogen.
– It burns with oxygen to produce water and forms explosive mixtures with air and chlorine.
– Hydrogen has specific combustion properties like an enthalpy of combustion of -286 kJ/mol and an autoignition temperature of 500°C.
Chemical Reactions and Compounds:
– Hydrogen forms compounds with elements like halogens, oxygen, carbon, and less electronegative elements.
– Hydrogen bonding is crucial for the stability of biological molecules.
– It forms hydrides with more electropositive elements, which can serve as bridging ligands in coordination complexes.
– Protons are central to acid-base reactions, and hydrogen is a critical component of acidic aqueous solutions.
Isotopes and Thermal/Physical Properties:
– Hydrogen has three isotopes: Hydrogen-1 (Protium), Hydrogen-2 (Deuterium), and Hydrogen-3 (Tritium).
– Deuterium is used in chemical experiments and as a neutron moderator, while Tritium is radioactive and used in luminous paint and nuclear fusion.
– The thermal and physical properties of hydrogen vary with temperature and are essential for industrial applications.
History, Discovery, and Applications:
– Hydrogen was discovered in the 17th century and identified as an element in the 18th century.
– It has a history of use in air travel, industrial applications, chemical labeling experiments, and as a clean energy source.
– Hydrogen-powered engines, airships, and various industrial applications have been developed over the years.
Quantum Theory and Cosmic Significance:
– Hydrogen plays a significant role in quantum theory, with its emission spectrum lines and behavior providing insights into atomic structure and chemical bonds.
– It is the most abundant element in the universe, crucial for star formation, nuclear fusion, and interstellar chemistry.
– Hydrogen’s prevalence in various states, from atomic to plasma, and its production methods contribute to its cosmic significance and potential future developments.
Hydrogen is a chemical element; it has symbol H and atomic number 1. It is the lightest element and, at standard conditions, is a gas of diatomic molecules with the formulaH2, sometimes called dihydrogen, but more commonly called hydrogen gas, molecular hydrogen or simply hydrogen. It is colorless, odorless, non-toxic, and highly combustible. Constituting about 75% of all normal matter, hydrogen is the most abundant chemical element in the universe. Stars, including the Sun, mainly consist of hydrogen in a plasma state, while on Earth, hydrogen is found in water, organic compounds, as dihydrogen, and in other molecular forms. The most common isotope of hydrogen (protium, 1H) consists of one proton, one electron, and no neutrons.
Hydrogen | ||||||||||||||||||||||||||
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Appearance | Colorless gas | |||||||||||||||||||||||||
Standard atomic weightAr°(H) | ||||||||||||||||||||||||||
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Hydrogen in the periodic table | ||||||||||||||||||||||||||
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Atomic number (Z) | 1 | |||||||||||||||||||||||||
Group | group 1: hydrogen and alkali metals | |||||||||||||||||||||||||
Period | period 1 | |||||||||||||||||||||||||
Block | s-block | |||||||||||||||||||||||||
Electron configuration | 1s1 | |||||||||||||||||||||||||
Electrons per shell | 1 | |||||||||||||||||||||||||
Physical properties | ||||||||||||||||||||||||||
Phaseat STP | gas | |||||||||||||||||||||||||
Melting point | (H2) 13.99 K (−259.16 °C, −434.49 °F) | |||||||||||||||||||||||||
Boiling point | (H2) 20.271 K (−252.879 °C, −423.182 °F) | |||||||||||||||||||||||||
Density (at STP) | 0.08988 g/L | |||||||||||||||||||||||||
when liquid (at m.p.) | 0.07 g/cm3 (solid: 0.0763 g/cm3) | |||||||||||||||||||||||||
when liquid (at b.p.) | 0.07099 g/cm3 | |||||||||||||||||||||||||
Triple point | 13.8033 K, 7.041 kPa | |||||||||||||||||||||||||
Critical point | 32.938 K, 1.2858 MPa | |||||||||||||||||||||||||
Heat of fusion | (H2) 0.117 kJ/mol | |||||||||||||||||||||||||
Heat of vaporization | (H2) 0.904 kJ/mol | |||||||||||||||||||||||||
Molar heat capacity | (H2) 28.836 J/(mol·K) | |||||||||||||||||||||||||
Vapor pressure
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Atomic properties | ||||||||||||||||||||||||||
Oxidation states | −1, 0, +1 (an amphoteric oxide) | |||||||||||||||||||||||||
Electronegativity | Pauling scale: 2.20 | |||||||||||||||||||||||||
Ionization energies |
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Covalent radius | 31±5 pm | |||||||||||||||||||||||||
Van der Waals radius | 120 pm | |||||||||||||||||||||||||
Spectral lines of hydrogen | ||||||||||||||||||||||||||
Other properties | ||||||||||||||||||||||||||
Natural occurrence | primordial | |||||||||||||||||||||||||
Crystal structure | hexagonal (hP4) | |||||||||||||||||||||||||
Lattice constants | a = 378.97 pm c = 618.31 pm (at triple point) | |||||||||||||||||||||||||
Thermal conductivity | 0.1805 W/(m⋅K) | |||||||||||||||||||||||||
Magnetic ordering | diamagnetic | |||||||||||||||||||||||||
Molar magnetic susceptibility | −3.98×10−6 cm3/mol (298 K) | |||||||||||||||||||||||||
Speed of sound | 1310 m/s (gas, 27 °C) | |||||||||||||||||||||||||
CAS Number | 12385-13-6 1333-74-0 (H2) | |||||||||||||||||||||||||
History | ||||||||||||||||||||||||||
Discovery | Henry Cavendish (1766) | |||||||||||||||||||||||||
Named by | Louis-Bernard Guyton de Morveau Antoine Lavoisier (1787) | |||||||||||||||||||||||||
Isotopes of hydrogen | ||||||||||||||||||||||||||
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In the early universe, the formation of hydrogen's protons occurred in the first second after the Big Bang; neutral hydrogen atoms only formed about 370,000 years later during the recombination epoch as the universe cooled and plasma had cooled enough for electrons to remain bound to protons. Hydrogen, typically nonmetallic except under extreme pressure, readily forms covalent bonds with most nonmetals, contributing to the formation of compounds like water and various organic substances. Its role is crucial in acid-base reactions, which mainly involve proton exchange among soluble molecules. In ionic compounds, hydrogen can take the form of either a negatively charged anion, where it is known as hydride, or as a positively charged cation, H+. The cation, usually just a proton (symbol p), exhibits specific behavior in aqueous solutions and in ionic compounds involves screening of its electric charge by surrounding polar molecules or anions. Hydrogen's unique position as the only neutral atom for which the Schrödinger equation can be directly solved, has significantly contributed to the foundational principles of quantum mechanics through the exploration of its energetics and chemical bonding.
Hydrogen gas was first produced artificially in the early 16th century by reacting acids with metals. Henry Cavendish, in 1766–81, identified hydrogen gas as a distinct substance and discovered its property of producing water when burned; hence its name means "water-former" in Greek.
Most hydrogen production occurs through steam reforming of natural gas; a smaller portion comes from energy-intensive methods such as the electrolysis of water. Its main industrial uses include fossil fuel processing, such as hydrocracking, and ammonia production, with emerging uses in fuel cells for electricity generation and as a heat source. When used in fuel cells, hydrogen's only emission at point of use is water vapor, though combustion can produce nitrogen oxides. Hydrogen's interaction with metals may cause embrittlement.
English
Etymology
From French hydrogène, coined by Louis-Bernard Guyton de Morveau, from Ancient Greek ὕδωρ (húdōr, “water”) + γεννάω (gennáō, “I bring forth”).